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The solution-processing of metal chalcogenides offers a promising route to improve the manufacturing of semiconductor devices. The amine–thiol solvent system has been deemed an “alkahest” for its ability to dissolve a wide range of metals and metal chalcogenides. Therefore, it enables convenient synthesis of metal sulfides. However, in the literature there are limited reports of analogous selenium-based “alkahest” chemistry. Here we show that solutions containing n-alkylammonium polyselenides can dissolve a wide range of metals and metal compounds through the formation of soluble metal polyselenides. These metal polyselenides can subsequently be utilized as precursors for the synthesis of a wide range of binary and multinary metal selenide thin films and nanoparticles, including Cu(In,Ga)Se2, Cu2ZnSnSe4, and Ag2ZnSnSe4.more » « less
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Deshmukh, Swapnil D.; Easterling, Leah F.; Manheim, Jeremy M.; LiBretto, Nicole J.; Weideman, Kyle G.; Miller, Jeffrey T.; Kenttämaa, Hilkka I.; Agrawal, Rakesh (, Inorganic Chemistry)
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Turnley, Jonathan W.; Deshmukh, Swapnil D.; Boulos, Victoria M.; Ellis, Ryan G.; LiBretto, Nicole J.; Liu, Judy Kuan-Yu; Miller, Jeffrey T.; Kenttämaa, Hilkka I.; Agrawal, Rakesh (, ACS Omega)
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Fabijanczuk, Kimberly; Yu, Zaikuan Josh; Bakestani, Rose M.; Murtada, Rayan; Denton, Nicholas; Gaspar, Kaylee; Otegui, Tara; Acosta, Jose; Kenttämaa, Hilkka I.; Eshuis, Henk; et al (, Analytical Chemistry)
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